Generalizing the Debye-Hückel equation in terms of density functional integral
نویسندگان
چکیده
منابع مشابه
Density fluctuations in an electrolyte from generalized Debye-Hückel theory.
Near-critical thermodynamics in the hard-sphere (1, 1) electrolyte is well described, at a classical level, by Debye-Hückel (DH) theory with s1, 2d ion pairing and dipolar-pair-ionic-fluid coupling. But DH-based theories do not address density fluctuations. Here density correlations are obtained by functional differentiation of DH theory generalized to nonuniform densities of various species. T...
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Article history: Received 27 February 2011 Revised 7 July 2011 Available online xxxx MSC: 31B10 35N25
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ژورنال
عنوان ژورنال: Physical Review E
سال: 2000
ISSN: 1063-651X,1095-3787
DOI: 10.1103/physreve.61.r6079